Towards sustainable management of polyacrylamide in soil-water environment: Occurrence, degradation, and risk.

Polyacrylamide (PAM) possesses unique characteristics, including high water solubility, elevated viscosity and effective flocculation capabilities. These properties make it valuable in various sectors like agriculture, wastewater treatment, enhanced oil recovery, and mineral processing industries, contributing to a continually expanding market. Despite its widespread use globally, understanding its environmental fate at the soil-water interface remains limited. This article aims to provide an overview of the occurrence, degradation pathways, toxicity, and risks associated with PAM in the bioenvironment. The findings indicate that various degradation pathways of PAM may occur in the bioenvironment through mechanical, thermal, chemical, photocatalytic degradation, and/or biodegradation. Through a series of degradation processes, PAM initially transforms into oligomers and acrylamide (AM). Subsequently, AM may undergo biodegradation, converting into acrylic acid (AA) and other compounds such as ammonia. Notably, among these degradation intermediates, AM demonstrates high biodegradability, and the bioaccumulations of both AM and AA are not considered significant. Ensuring the sustainable use of PAM necessitates a comprehensive understanding among policymakers, scholars, and industry professionals regarding PAM, encompassing its properties, applications, degradation pathways, toxic effect on humans and the environment, and relevant regulations. Additionally, this study offers insights into future priority research directions, such as establishing of a reliable source-to-destination supply chain system, determining the maximum allowable amount for PAM in farmlands, and conducting long-term trials for the PAM-containing demolition residues.

Unraveling the Potential of Electrochemical pH-Swing Processes for Carbon Dioxide Capture and Utilization.

Global warming, driven by the accumulation of anthropogenic greenhouse gases, particularly CO2, in the atmosphere, has garnered significant attention due to its detrimental environmental impacts. To combat this critical issue, the deployment of CO2 capture and utilization (CCU) strategies has been considered as one of the technology-based solutions, leading to extensive scientific and engineering research. Electrochemical pH-swing (EPS) processes offer a promising approach to diverse CCU pathways, such as the delivery of pure CO2 gas, the delivery of bicarbonate (e.g., for microalgae cultivation), and the formation of carbonate minerals. In this study, we discuss several CCU pathways using EPS and provide an in-depth analysis of its mechanisms and potential applications, outlining its limitations from both thermodynamic and kinetic standpoints. The EPS process has demonstrated remarkable capabilities, achieving a CO2 capture efficiency of over 90% and unlocking valuable opportunities for CCU applications. We also develop an initial techno-economic assessment and provide the perspectives and challenges for future development and deployment of EPS. This study sheds light on the integration of EPS with CCU, closing the carbon cycle by effectively utilizing the products generated through the process, such as carbonate minerals and bicarbonate solution. For instance, the bicarbonate product can serve as a viable feedstock for bicarbonate-based microalgae production systems, with the added benefit of reducing costs by 40-80% compared to traditional gaseous CO2 delivery approaches. By integration of electrochemical technologies with CCU methods, this study underscores the immense potential for mitigating CO2 emissions and advancing sustainable practices to combat global warming. This study not only addresses the urgent need for effective solutions but also paves the way for a greener and more sustainable future.

Enhanced biomethane production with a low carbon footprint via anaerobic co-digestion of swine wastewater with rice husk.

An electricity-assisted anaerobic co-digestion (EAAD) process was developed and compared with conventional anaerobic co-digestion (AD) using piggery wastewater and rice husk as feedstocks. Various methodologies, including kinetic models, microbial community analyses, life-cycle carbon footprints, and preliminary economic analysis, were integrated to comprehensively evaluate the performance of the two processes. The results demonstrated that EAAD exhibited a positive improvement of 2.6 % to 14.5 % in biogas production compared to AD. The suitable wastewater-to-husk ratio for EAAD was found to be 3:1, which corresponded to a carbon-to­nitrogen ratio of approximately 14. This ratio demonstrated positive co-digestion effects and electrical enhancements in the process. According to the modified Gompertz kinetics, the biogas production rate in EAAD ranged from 1.87 to 5.23 mL/g-VS/d, significantly higher than the range of 1.19 to 3.74 mL/g-VS/d observed in AD. The study also investigated the contributions of acetoclastic and hydrogenotrophic methanogens to biomethane formation, revealing that acetoclastic methanogens accounted for 56.6 % ± 0.6 % of the methane production, while hydrogenotrophic methanogens contributed to 43.4 % ± 0.6 %. No significant difference in the methanogenic reaction pathways was observed between AD and EAAD, indicating that the introduction of an external electric field did not alter the predominant pathways (p > 0.05, two-sample t-test). Furthermore, retrofitting existing AD plants with EAAD units can reduce the carbon intensity of piggery wastewater treatment by 17.6 % to 21.7 %. The preliminary economic analysis indicated a benefit-cost ratio of 1.33 for EAAD, confirming the feasibility of implementing EAAD for wastewater treatment while simultaneously producing bioenergy. Overall, this study provides valuable insights into upgrading the performance of existing AD plants by introducing an external electric field. It demonstrates that EAAD can achieve higher and cost-effective biogas production with a lower life-cycle carbon footprint, thus enhancing the sustainability and efficiency of the biogas production process.

Chitosan cross-linked ß-cyclodextrin polymeric adsorbent for the removal of perfluorobutanesulfonate from aqueous solution: adsorption kinetics, isotherm, and mechanism.

The existence of per- and polyfluoroalkyl substances (PFASs) in water is of serious interest due to their toxic, bioaccumulative, and persistent nature, and adsorption is an effective approach for the PFASs removal. In the present study, we developed a polymeric adsorbent by cross-linking chitosan and ß-cyclodextrin using glutaraldehyde (Chi-Glu-ß-CD) and evaluated its removal performance for perfluorobutanesulfonate (PFBS) from water. The results indicate that the performance was highly affected by solution pH; under a more acidic condition (e.g., pH 2.0), a higher removal efficiency was detected, and faster adsorption kinetics was observed with the rate constant (k2) of 0.001 ± 3×10-4 g mg-1 min-1. Adsorption isotherm data agreed to the Sips model with a maximum heterogeneous adsorption capacity of 135.70 ± 25.70 mg g-1, probably due to protonated amine (NH+) and electron-deficient ß-CD cavities. The adsorption mechanism was confirmed using energy dispersive X-ray and Fourier transform infrared (FTIR) spectroscopy, showing the role of electrostatic attractions between the protonated amine and the negatively charged PFBS molecule (especially, with sulfonate side (N-H--O-S)) and host-guest inclusion formations with ß-CD cavity in adsorption. Additionally, the synthesized adsorbent was recovered using methanol without any significant decline in adsorption efficiency even after four continuous adsorption/desorption cycles. All these findings suggested that the Chi-Glu-ß-CD composite could be a promising adsorbent in the removal of PFBS from water.

Catalytic Processes to Accelerate Decarbonization in a Net-Zero Carbon World.

Reducing carbon dioxide emissions is one of the critical challenges to mitigate global climate change, which is having detrimental impacts on society and the environment. Fossil fuel combustion in transportation, power generation, and industrial processes is the dominant contributor to carbon emissions. Over the past decades, sustainable solutions and strategies have been investigated and developed to enable decarbonization. Catalysis plays an essential role to address this global challenge by increasing energy efficiency, reducing carbon emissions, capturing carbon dioxide, and utilizing clean energy sources to displace fossil fuels. In this Review, the role of catalysis in reducing energy demand was discussed, enhancing process efficiency, displacing carbon-intensive feedstocks and products, and therefore, reducing carbon emissions. Recent advances in catalyst development were summarized, focusing on applications to enhance industrial processes efficiency and enable utilization of clean energy sources. Emerging approaches in catalysis were reviewed, including the manufacture of iron and steel, direct air capture of CO2 , production of ethylene, ammonia, and sustainable aviation fuels, plastic recycling, and the synthesis of biobased plastics. The Review was concluded with suggested research directions to achieve a carbon net-zero world.

Anaerobic swine digestate valorization via energy-efficient electrodialysis for nutrient recovery and water reclamation.

The development of cost-effective and energy-efficient technologies to recover nutrients from digestate is important. Anaerobic digestate can be concentrated into bio-nutrient products through an electrodialysis (ED) process in an energy-efficient manner. Despite recent advances, the operation modes of ED for nutrient recovery from swine digestate are yet to be systematically evaluated from the perspective of energy-water efficiencies, and the determination of optimal operations in ED units is still ambiguous. In this study, two different operating modes of electrodialysis, i.e., constant voltage and constant current, are designed to evaluate the energy efficiency and effectiveness of nutrient recovery from anaerobic swine digestate. The ion removal ratio and current efficiency of the different modes and their associated electromigration performance (e.g., rate constants) are evaluated. The results indicate that the maximum removal efficiency (in terms of electrical conductivity) is 92.8% at a cell voltage of 2.4 V/cell using the constant voltage operation. The current efficiencies of NH4+ (43‒65%) are higher than that of other ions, such as K+ (12‒19%), Cl- (4‒7%), and PO43- (0.1‒1.5%). For nitrogen recovery, the required energy consumption was about 0.24‒15.2 kWh/kg-N (0.86‒54.7 kJ/g-N), corresponding to a removal ratio of ammonium from 70.8% to 99.1%. Based on the experimental data, the optimal operating conditions are identified using response surface models by considering process energy consumption and productivity to deliver energy-efficient nutrient separation. One candidate of the ideal conditions to achieve the total ion removal of ∼93% should be operated at a constant cell voltage of 1.15 V, corresponding to a productivity of 5.24 gal/hr/m2 at an energy consumption of 0.44 kWh/m3. Last, a conceptual design of cascading separation processes is proposed for digestate valorization as biofertilizers, nutrients, organic acids, and reclaimed water. A preliminary benefit-cost evaluation is then performed to evaluate the engineering and economic performance of the developed process for nutrient recovery from swine digestate. This article provides insight into practical large-scale applications of digestate valorization through energy-efficient separation, thereby realizing a circular economy system and a decarbonizing supply chain of bio-nutrients.

An overview of deploying membrane bioreactors in saline wastewater treatment from perspectives of microbial and treatment performance.

The discharged saline wastewater has severely influenced the aquatic environment as the treatment performance of many wastewater treatment techniques is limited. In addition, the sources of saline wastewater are also plentiful from agricultural and various industrial fields such as food processing, tannery, pharmaceutical, etc. Although high salinity levels negatively impact the performance of both physicochemical and biological processes, membrane bioreactor (MBR) processes are considered as a potential technology to treat saline wastewater under different salinity levels depending on the adaption of the microbial community. Therefore, this study aims to systematically review the application of MBR widely used in the saline wastewater treatment from the perspectives of microbial structure and treatment efficiencies. At last, the concept of carbon dioxide capture and storage will be proposed for the MBR-treating saline wastewater technologies and considered toward the circular economy with the target of zero emission.

Food waste and soybean curd residue composting by black soldier fly.

This study attempted to manage the food waste and soybean curd residue generated in Taiwan's National Ilan University by black soldier fly-aided co-composting. The food waste and soybean curd residue were co-composted with rice husk as a bulking agent in 4:1 ratio and 0.42 mg BSF/g waste. The higher organic matter degradation of 31.9% was found in Container B (black soldier flies aided food waste and rice husk co-composting) with a rate constant of 0.14 d-1. In Container D (black soldier flies aided soybean curd residue and rice husk co-composting), the organic matter degradation of 29.4% was found with a rate constant of 0.29 d-1. The matured compost of 6.02 kg was obtained from 20 kg of food waste, while 5.83 kg of matured compost was generated from 20 kg of soybean curd residue. The physico-chemical parameters of the final matured compost were in the favorable range of Taiwan's compost standards. The germination index was 188.6% and 194.78% in Containers B and D, respectively. The present study will expand the application of BSF at the institutional level which prove to be a feasible solution for rapid, clean, and efficient composting of post-consumer food wastes.

Evaluation of the dual-process approach for in-situ groundwater arsenic removal.

While the worldwide distribution of geogenic arsenic (As)-affected groundwater is highly overlapped with the areas with abundant groundwater, utilization of As-contained groundwater is an inevitable compromise in those areas where surface water is not enough for irrigation. Since the occurrence of As in groundwater is often accompanied by high iron (Fe) contents, the facilitation of As and Fe precipitation without adding additional oxidizers and adsorbents is considered an environmental-friendly approach to removing As in groundwater. In the present study, the oxidation/filtration dual-process with sprinkling height of 25 cm and 120 kg filter media efficiently increased the dissolved oxygen (DO) concentration (0.36-1.52 mg/L) and oxidation-reduction potential (ORP) (24-63 mV), which facilitated the formation of Fe oxides and As co-precipitation. The correlation of As removal efficiencies with their respective flow rates indicated that a decrease in groundwater Fe and an increase of Fe in sands and gravels filters as the flow rate increased evidenced the rapid oxidation of Fe to form the Fe hydroxides. In a 40-hour continuous aeration/filtration operation, As and Fe concentrations in groundwater were reduced by 79.5% and 64.88% within 40 hrs, respectively. The ease of filter replacement and cost-effectiveness in operation can be the major attractions and innovations for future field practices.

Environmental benefit assessment of steel slag utilization and carbonation: A systematic review.

The rapid increase in steel slag generation globally highlights the urgent need to manage the disposal or utilization processes. In addition to conventional landfill disposal, researchers have successfully reused steel slag in the construction, chemical, and agricultural fields. With the large portions of alkaline silicate mineral content, steel slag can also be used as a suitable material for carbon capture to mitigate global warming. This article comprehensively reviews the environmental performance of steel slag utilization, especially emphasizing quantitative evaluation using life cycle assessment. This paper first illustrates the production processes, properties, and applications of steel slag, and then summarizes the key findings of the environmental benefits for steel slag utilization using life cycle assessment from the reviewed literature. This paper also identifies the limitations of quantifying the environmental benefits using life cycle assessment. The results indicate steel slag is largely utilized in pavement concrete and/or block as a substitution for natural aggregates. The associated environmental benefits are mostly attributed to the avoidance of the large amount of cement utilized. The environmental benefits for the substitution of traditional energy-intensive material and carbonation treatment are further discussed in detail. Due to the presence of heavy metals, the potential risks to human and ecological health caused by the manufacturing process and usage stage are examined. Finally, the current challenges and global social implications for steel slag valorization are summarized.

Anaerobic co-digestion of agricultural wastes toward circular bioeconomy.

A huge amount of agricultural wastes and waste activated-sludge are being generated every year around the world. Anaerobic co-digestion (AcD) has been considered as an alternative for the utilization of organic matters from such organic wastes by producing bioenergy and biochemicals to realize a circular bioeconomy. Despite recent advancement in AcD processes, the effect of feedstock compositions and operating conditions on the biomethane production processe has not been critically explored. In this paper, we have reviewed the effects of feedstock (organic wastes) characteristics, including particle size, carbon-to-nitrogen ratio, and pretreatment options, on the performance of an anaerobic digestion process. In addition, we provided an overview of the effect of key control parameters, including retention time, temperature, pH of digestate, volatile fatty acids content, total solids content, and organic loading rate. Lastly, based on the findings from the literature, we have presented several perspectives and prospects on priority research to promote AcD to a steppingstone for a circular bioeconomy.

Systematic approach to source-sink apportionment of copper in paddy fields: Experimental observation, dynamic modeling and prevention strategy.

The accumulation of heavy metals in paddy rice severely impacts the health of consumers and plants. In this study, a systematic approach to source-sink apportionment of copper in paddy fields was developed by considering all bioenvironmental interfaces. Experimental data from two experimental fields (namely Field A and Field B) in the first harvest period was collected. Then, mass-balance-based models with dynamic critical loads were established to evaluate the year of excess for copper. The results indicated that irrigation water contributed the highest portion (96.2-98.8%) of total copper inputs. Under the business-as-usual scenario, the soil copper concentration of Field A and Field B might exceed the Taiwanese national standard within 66 and 24 years, respectively. In addition, alternate wet-dry irrigation was found to be one of the total solutions to reducing copper accumulation in soils by 17-48%. It could also provide a significant reduction of water usage in paddy fields by ~25%, thereby increasing the resilience to extreme climate change events. Lastly, based on the field observations, three improvement strategies on sustaining soil quality towards better agricultural environment were proposed. The connection of copper accumulation in soils with dietary and ecological risks was also briefly illustrated.

Contribution of sewage to occurrence of phosphodiesterase-5 inhibitors in natural water.

Phosphodiesterase-5 inhibitors (PDE-5i, such as Sildenafil, Tadalafil and Vardenafil, mainly prescribed to treat erectile dysfunction) and their generic drug equivalents have been widely marketed and consumed in Korea. From the concentrations detected in wastewater, we could deduce that relatively large amounts of PDE-5i were consumed without a legal prescription. Thus, PDE-5i's presence in the environment via sewage is unavoidable, and their environmental fate within a sewage treatment plant (STP) should be evaluated. In this study, we investigated the occurrence of three PDE-5i analogs in the influent and effluent of two STPs and the receiving water bodies. The PDE-5i concentration in total reached 62 ± 12 (STP#1) and 88 ± 37 ng L-1 (STP#2) in the sewage influent; about 70% of it was Sildenafil in both STPs. However, they were hardly removed by the STPs as the removal efficiency of the STPs was less than 10% ± 5%. Therefore, the pharmaceuticals were detected in the receiving water (lower than 7 ng L-1as a total amount) and the concentration slightly increased downstream of the STPs. A simple mass balance model applied for the compounds in the STP effluent and receiving water bodies also confirmed that the discharged PDE-5i were quite persistent. Lastly, we identified temporal and regional patterns in the consumption of the drugs from daily variations of PDE-5i in the influent to these two STPs. For instance, the levels of PDE-5i in the sewage significantly increased on weekends (from Friday to Saturday), and especially in the area where adult-entertainment businesses are common. We estimated that the amount of PDE-5i consumption in this area was 31% higher than that in the area with fewer nightlife spots. Considering that they are pharmaceutically active and resistant to treatment processes within an STP, it is advised that a regular monitoring and management program for PDE-5i should be developed to prevent the discharge of the pharmaceuticals into the water environment.

Non-conventional water reuse in agriculture: A circular water economy.

Due to the growing and diverse demands on water supply, exploitation of non-conventional sources of water has received much attention. Since water consumption for irrigation is the major contributor to total water withdrawal, the utilization of non-conventional sources of water for the purpose of irrigation is critical to assuring the sustainability of water resources. Although numerous studies have been conducted to evaluate and manage non-conventional water sources, little research has reviewed the suitability of available water technologies for improving water quality, so that water reclaimed from non-conventional supplies could be an alternative water resource for irrigation. This article provides a systematic overview of all aspects of regulation, technology and management to enable the innovative technology, thereby promoting and facilitating the reuse of non-conventional water. The study first reviews the requirements for water quantity and quality (i.e., physical, chemical, and biological parameters) for agricultural irrigation. Five candidate sources of non-conventional water were evaluated in terms of quantity and quality, namely rainfall/stormwater runoff, industrial cooling water, hydraulic fracturing wastewater, process wastewater, and domestic sewage. Water quality issues, such as suspended solids, biochemical/chemical oxygen demand, total dissolved solids, total nitrogen, bacteria, and emerging contaminates, were assessed. Available technologies for improving the quality of non-conventional water were comprehensively investigated. The potential risks to plants, human health, and the environment posed by non-conventional water reuse for irrigation are also discussed. Lastly, three priority research directions, including efficient collection of non-conventional water, design of fit-for-purpose treatment, and deployment of energy-efficient processes, were proposed to provide guidance on the potential for future research.

Mercury vapor adsorption and sustainable recovery using novel electrothermal swing system with gold-electrodeposited activated carbon fiber cloth.

A novel electrothermal swing (ETS) system with gold-electrodeposited activated carbon fiber cloth (GE-ACFC) was developed to adsorb and sustainably recover low-concentration Hg0. GE-ACFC with an Au growth time of 1200 s displayed the largest Hg0 adsorption capacity and >90% removal efficiency. The Hg0 adsorption of GE-ACFC was dominated by physisorption via Au amalgamation. In contrast, Hg adsorption of untreated ACFC (RAW-ACFC) was mainly controlled by physisorption and chemisorption related to carbonyl groups. Nevertheless, both ACFCs could reach 100% ETS Hg0 regeneration. The Hg re-adsorption of GE-ACFC was stable, with efficiency >90% at different regeneration temperatures in three-cycle ETS experiments, but the Hg re-adsorption efficiencies of RAW-ACFC greatly decreased to only 60% after 250 â„ƒ regeneration, due to the formation of electrothermal hot spots in the ACFC. Because the thermal and electrical conductivity of GE-ACFC increased due to Au electrodeposition, the presence of electrothermal hot spots in GE-ACFC-1200s was minor. Simulation results showed that both pseudo-first-order and pseudo-second-order models fitted well to the desorption patterns of the GE-ACFC. Mass transfer model further suggested that intraparticle diffusion control was the rate-limiting step, with diffusion coefficients increased from the first to the third cycle for GE-ACFC.

Composition-oriented estimation of biogas production from major culinary wastes in an anaerobic bioreactor and its associated CO2 reduction potential.

Despite the wide applications of dry anaerobic digestion (AD), a number of fundamental issues, such as composition-oriented estimation of biogas production and CO2 reduction potential, were not well understood yet. The objective of this study was to establish composition-oriented models for prediction of biogas production and the associated shift of microbial communities. Three important factors regarding feedstock, including loading, carbon-to-nitrogen ratio, and solid-to-liquid ratio, were found to significantly affect the biogas production. The biogas production and digestion kinetics were evaluated with the response surface methodology. The major contribution to biogas production was found to be hydrogenotrophic methanogens (82.6 ± 0.4%). The net CO2 reduction potential was assessed from the life-cycle approach, and a substantial amount of CO2 generation (i.e., 2.8-6.7 tonne/tonne-VS) could be reduced by AD, compared to incineration, revealing that dry AD for food waste treatment should be one of the essential practices in the portfolio of global CO2 mitigation.

Brackish water desalination using reverse osmosis and capacitive deionization at the water-energy nexus.

In this article, we present a critical review of the reported performance of reverse osmosis (RO) and capacitive deionization (CDI) for brackish water (salinity < 5.0 g/L) desalination from the aspects of engineering, energy, economy and environment. We first illustrate the criteria and the key performance indicators to evaluate the performance of brackish water desalination. We then systematically summarize technological information of RO and CDI, focusing on the effect of key parameters on desalination performance, as well as energy-water efficiency, economic costs and environmental impacts (including carbon footprint). We provide in-depth discussion on the interconnectivity between desalination and energy, and the trade-off between kinetics and energetics for RO and CDI as critical factors for comparison. We also critique the results of technical-economic assessment for RO and CDI plants in the context of large-scale deployment, with focus on lifetime-oriented consideration to total costs, balance between energy efficiency and clean water production, and pretreatment/post-treatment requirements. Finally, we illustrate the challenges and opportunities for future brackish water desalination, including hybridization for energy-efficient brackish water desalination, co-removal of specific components in brackish water, and sustainable brine management with innovative utilization. Our study reveals that both RO and CDI should play important roles in water reclamation and resource recovery from brackish water, especially for inland cities or rural regions.

Addressing environmental sustainability of plasma vitrification technology for stabilization of municipal solid waste incineration fly ash.

Fly ash from municipal solid waste incineration is considered as a hazardous waste, which would raise great threats on environmental safety due to the inherent toxic heavy metals and organic pollutants. In this study, we applied the life cycle assessment to evaluate the thermal plasma vitrification process for stabilization of fly ash from municipal solid waste incineration. We established four scenarios: (i) plasma vitrification, including centralized and off-site plasma treatment, (ii) fuel-based vitrification, (iii) water-washing treatment followed by a rotary kiln, and (iv) conventional solidification and landfill. We found that the environmental impacts, especially toxicity to ecosystem quality and human health, could be significantly reduced by deploying plasma vitrification technology. We also found that centralized plasma vitrification facilities possessing larger treatment capabilities with clean electricity could further reduce the environmental impacts. In contrast, the water-washing treatment exhibited the highest environmental impacts due to the emissions of vaporized heavy metals. Based on the LCA and sensitivity analysis, we confirmed that the thermal plasma vitrification should be considered as an environmentally-friendly solution to sustainable treatment of fly ash from municipal solid waste incineration. Lastly, we provided several perspectives and prospects of plasma vitrification for realizing the sustainable materials management.

Enhanced removal of tris(2-chloroethyl) phosphate using a resin-based nanocomposite hydrated iron oxide through a Fenton-like process: Capacity evaluation and pathways.

The effective removal of organophosphorus compounds (OPs) effectively from water environment remains an important but challenging task. In this study, a resin-based nanocomposite of hydrated iron oxide (HD1) was used as Fenton-like catalyst for effectively catalyzing the decomposition of hydrogen peroxide to degrade tris(2-chloroethyl) phosphate (TCEP). The results showed that HD1 was successfully prepared, which had great versatility, catalytic performance and adsorption capacity. Besides, HD1/H2O2 was capable of degrading TCEP completely with less than 0.2 mg/L of inorganic phosphorus (IP) in the effluent at the initial TCEP of 38 mg/L, pH = 4, H2O2 dosage of 20 mM, and the Kobs could result in about 1.0530 min-1 under identical conditions. More attractively, inorganic ions (i.e., Cl-, CO32-, SO42-, NO3-, HCO3-, Ca2+, and Mg2+) exhibited moderate effect on TCEP degradation. The negative effect of natural organic matters (NOM) (i.e., HA) on the degradation of TCEP was responsible for competition for the active oxygen species. Combined with electron paramagnetic resonance (EPR) spectra, X-ray photoelectron spectroscopy (XPS) and other analytical methods and radical quenching experiments, the possible removal process of TCEP was discussed, including two processes of oxidative degradation and immobilization of IP. Besides, hydroxyl radicals (•OH) was the key active species that contributed to TCEP degradation through hydroxylation-oxidation and C-O bond cracking, and specificity adsorption of HFO on IP was revealed. Furthermore, the results showed that HD1 had desirable acid and alkali resistance. In the continuous running fixed bed column experiment, HD1 showed a satisfactory performance in cycle operations. This work proposed a new enhanced process for removing TCEP in water environment by HD1/H2O2, and the multi-functional material, HD1 was promising in treatment of water containing organic phosphorus pollutants. This will be believed that this study will provide new ideas and new materials for the treatment of organic phosphorus-based organic pollutants, and lay the foundation for further deepening and expanding the application of adsorption resins in the field of water pollution control.

Implementation of green chemistry principles in circular economy system towards sustainable development goals: Challenges and perspectives.

Green chemistry principles (GCP) are comprehensively deployed in industrial management, governmental policy, educational practice, and technology development around the world. Circular economy always aims to balance the economic growth, resource sustainability, and environmental protection. This article offers a highlight on issues of significance within GCP and circular economy, and proposes the integrated strategies for GCP implementation from the aspects of governance, industry and education. At first, we developed a new categorizing system for GCP dividing to (i) pollution and accident prevention, (ii) safety and resource sustainability, and (iii) energy and resource sustainability. To assess the GCP practice towards the circular economy, the implementation of international movement of GCP in worldwide policy, especially those of Canada, China, Germany, Japan, South Korea, Sweden, Taiwan, United States and United Kingdom were reviewed. The policy implementation of GCP practices among governance, industries and education was analyzed. To integrate GCP into the circular economy concept, we also proposed five strategies of priority governance direction as follows: (i) establishment of cross-departmental collaboration, (ii) development of cleaner production and green product, (iii) provision of integrated chemical management system, (iv) implementation of green chemistry education program, and (v) construction of a business model. Finally, we discussed the prospects of disciplinary elements including the establishment of redesign-reduction-recovery-recycle-reuse (5R) practices for wastes reclamation, deployment of water-energy-food nexus with GCP to improve the food security and resource sustainability, and implementation of GCP in the green smart industrial park.